Processes in Microsoft 365 for setting up Office apps, redeeming product keys, and activating licenses.
Hello Quincy,
Based on your description " when adding the new user to the child domain OU" then you got the error above, may I know what the child domain OU means?
Generally, if you only need to add the child domain to Exchange and AD under Primary domain, first you could add a domain suffix in AD environment, and also add the child domain in Exchange server as an accepted domain for mail flow purpose. However, according to my tests in my lab. When creating new users (or mailbox) with the new child domain, the user objects would be put in an OU under the primary domain. For example I have a primary domain contoso.com, and the child domain is child.contoso.com, the user with this child domain need to be put in the OU under contoso.com but not the child.contoso.com. If you need to create users with child.contoso.com and also put the user in the OU under child.contoso.com, you would need to establish another DC put in the same forest in AD, then you could be able to do that. By the way, for the command you mentioned above, as far as I know it is used to refresh and extend the AD domain schema when you have already installed Exchange server in the environment. Generally it would not affect the existing domain schema. For more details, please refer to https://docs.microsoft.com/en-us/Exchange/plan-and-deploy/prepare-ad-and-domains?view=exchserver-2019.
Please feel free to let me know if you have any other concern, thanks.
Best Regards,
Oliver