Dear Cindy,
Good day! Thank you for posting in Microsoft Community.
Unfortunately, we can’t insert automatic numberings with letters in Excel spreadsheet
We understand the inconvenience and apologize for it. To address your concern about the situation, we’d kindly suggest you leave a feedback in Excel: How do I give feedback on Microsoft Office?
As a workaround for this you may try to use a formula to combine the cells:
In a workbook column and insert the letters in alphabetical order.
In the column where you want to insert numbering type a formula. Please check the example below, in my example is =1&E1

Click on a cell and drag it down to auto populate the column:

Sincerely,
Igor | Microsoft Community Moderator
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