Dear Jonathan McInerny,
Good day! Thank you for posting to Microsoft Community. We are happy to help you.
We don't seem to have received a screenshot of you. At the same time, it should be noted that Office applications must be activated independently, which means that even if you log in to the Windows system, you still need to log in to the Office application to activate the Office applications.
If you are convenient, please provide a screenshot of the error message and a screenshot of the subscription information page: Manage your Microsoft 365 subscription - Microsoft Support
Sincerely,
Tin | Microsoft Community Moderator