Dear LosMartinos,
Good day! Thank you for posting to Microsoft Community. We are happy to help you
I noticed that you mentioned that workbooks in SharePoint can no longer be opened in the synchronization library. I've also noticed this happening in Office 2016 and Office 2019.
First of all, Office 2016 and Office 2019 are typically personal subscriptions that are activated by your personal account, while SharePoint Online is business subscriptions that are activated by your work account. So when you were using a personal subscription account, you didn't have access to the SharePoint document library directly. To test this hypothesis, I'd like to know if you can access the SharePoint document library on the web side and edit permissions by activating Office 2019. If you still can't, then this account doesn't have corresponding permissions.
If you do not experience this phenomenon on the web side and can edit normally, please try resetting OneDrive - Microsoft Support. Then resynchronize the document library to see the results.
If you still encounter this phenomenon, please also share the specific screenshot of the error message with us.
Sincerely,
Tin | Microsoft Community Moderator