Hi @HamoudaAlbakri-3924,
Remember that DFS Namespace and DFS Replication are two (2) different roles.
You need to make sure you have installed the DFS Namespace role on your Windows Server 2019, and then make sure to add your Windows Server 2019 server as a DFS Namespace member server to your existing DFS Namespace.
Once the above are done, go to the DFS Management console, under your namespace go to Namespace Servers, enable your Windows Server 2019 as a namespace server, and disable your Windows Server 2012 R2 server.
I would then recommend to leave your old server disabled for a day or more to make sure there are no connections towards it, after that it should be safe to demote your old Windows Server 2012 R2 server. Also remember to remove your old server from the DFS Replication group.
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Best regards,
Leon