A Microsoft file hosting and synchronization service.
Hello there,
Yes, OneDrive is designed to synchronize files between your computer and the cloud storage associated with your Microsoft accounts, whether they are business or personal accounts. When you log in to your computer using your Microsoft 365 business account, the files associated with that account will be synced to your OneDrive folder on the computer. Similarly, when you log out and log back in using your personal Microsoft 365 account, the files associated with your personal account will be synced to the same OneDrive folder on your computer.
OneDrive keeps the files from each account separate and organizes them within the OneDrive folder. This means that your frequently used work files and your frequently used personal files will be stored on the same computer, but they will be stored in separate folders within the OneDrive directory. This way, you can easily access and manage both sets of files without any overlap or confusion.
It's important to note that OneDrive synchronizes files to the cloud automatically whenever there is an internet connection available. So, any changes made to your files while working with your business or personal accounts will be synced to the cloud, ensuring that you have access to the latest versions of your files from any device connected to the internet.
To learn more about using OneDrive with multiple accounts and how synchronization works, you can visit the official Microsoft support page for OneDrive: https://support.microsoft.com/en-us/onedrive
I provided you a similar topic that could possibly help you, quick fixes and troubleshooting found here: (Combining Microsoft accounts) https://support.microsoft.com/en-us/account-billing/combining-microsoft-accounts-06b122ca-7323-48f5-8cd7-c3408bcc2123#:~:text=You%20can%20use%20OneDrive%20to,files%20from%20one%20to%20another.
I hope this information helps you understand how OneDrive synchronizes files on your computer for both business and personal accounts. If you have any further questions or need more assistance, feel free to ask.
Best regards, Ivan