Windows has no control over the actions associated to the function keys on your keyboard, that is always controlled by the PC manufacturer because the actions associated to the keys vary from PC to PC.
1
Press Fn + Esc on your keyboard to test if that toggles the Function Lock on your keyboard off.
2
If not, boot your system into BIOS.
Look for a setting in there to toggle between Function Keys and Media/Action Keys and apply that.
3
If that does not resolve the problem, I need some information about your system, click your Start Button, then just type msinfo and press Enter, please provide a screenshot of the resulting System Information window.