Try this script:
select top(1) @segmentdetails = from_airport + '/' + to_airport from @TEMP order by SegmentId
select @segmentdetails = @segmentdetails + '/' + to_airport from @TEMP order by SegmentId offset 1 row
select @segmentdetails
and this:
select @segmentdetails = concat( (select top(1) from_airport from @TEMP order by SegmentId), '/', string_agg(to_airport, '/') within group (order by SegmentId))
from @TEMP
select @segmentdetails