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Hi,
set StartupUri in App.xaml (C#) or Application.xaml (VB):
<Application x:Class="WpfApp1.App"
xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
xmlns:local="clr-namespace:WpfApp1"
StartupUri="Window075.xaml"/>