How about this?
$string = "abc"
"Unicode format"
$string | format-hex -Encoding Unicode
$bytes = ConvertFrom-StringToByteArray -String $string -Encoding BigEndianUnicode
""
"BigEndian format"
$bytes | format-hex
Produces...
Unicode format
00 01 02 03 04 05 06 07 08 09 0A 0B 0C 0D 0E 0F
00000000 61 00 62 00 63 00 a.b.c.
BigEndian format
Path:
00 01 02 03 04 05 06 07 08 09 0A 0B 0C 0D 0E 0F
00000000 00 61 00 62 00 63 .a.b.c
PS C:\>