Hello @Ukarande, Vaibhav Welcome to Microsoft Q&A community forum!
As per support matrix - https://learn.microsoft.com/en-us/azure/site-recovery/azure-to-azure-support-matrix "Availability scenario - supported. Scalability scenario - not supported." meaning you can enable replication for VMSS VMs but cannot scale these VMs as per your requirement.
Hope that answers your questions!
----------------------------------------------------------------------------------------------------------------------
If the response helped, do "Accept Answer" and up-vote it