You can do :
colors(0) = ColorTranslator.ToOle(Color.Teal)
colors(1) = ColorTranslator.ToOle(Color.AntiqueWhite)
colors(2) = ColorTranslator.ToOle(Color.Brown)
colors(3) = ColorTranslator.ToOle(Color.Aquamarine)
colors(4) = ColorTranslator.ToOle(Color.BlanchedAlmond)