Hi there,
Your best option is to create DNS records so that \oldserver points to your DFS namespace. You could do a couple of ways but the easiest might be to create a CNAME record.
The original \server\share paths don't go away, in fact, they are necessary for DFS to work. You can still have clients point to them. You just don't get the benefit of failover. I have a few clients that still point to the original \server\share UNC paths, particularly for things like Folder Redirection with Offline Files, Offline Files often don't play nice with DFS.
Additionally, DFS replication works between targets in the namespace regardless of whether a client connects via the namespace UNC or the server UNC.
Actually moving clients depends on how you present the shares. If they are drive letters, then your Group Policy or logon script can simply be modified to point to the DFS UNC. If you access UNCs via links within documents or SharePoint, it can get messy. There used to be tools that would find & replace UNCs within documents.
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