You need to make sure Server B is also published on the Internet. There exists public DNS records (mail.domain.com, autodiscover.domain.com, MX) point the server B.
Mark sure MRSProxy is enabled on server B and there exist an admin account hosted on server B.
Get-WebServicesVirtualDirectory | Format-Table -Auto Identity,MRSProxyEnabled
Then you will could rerun HCW to choose server B as the hybrid endpoint.
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