Network connection block or reset logging is not currently available through sysmon. Within sysmon the closest I would think you could get is to monitor for dns query activity which is not followed by network connection to corresponding dns query result ip.
For blocking events I would focus on correlation of logs from host or network firewall or intrusion detection applications. For reset events i would consider monitoring of protocol analysis such as netflow or splunk stream.
It would be cool if sysmon had a way of capturing such events though.