
Hi @Bhargav Prasad ,
Per my test, We can use GetSharingInformation
to retrieve Expiration. You can refer to following url
_api/web/Lists(<guid>)/GetItemById(<itemid>)/GetSharingInformation?$Expand=permissionsInformation,pickerSettings
It will return all the links and users information. If the url wasn't set Expiration date the property will be null
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