Hello @Adam Postgate
Try and mount the wim manually with imagex. If you get an error with access denied or file not found then it is most likely a antivirus program blocking the acces.
ImageX: https://learn.microsoft.com/en-us/previous-versions/windows/it-pro/windows-7/dd744377(v=ws.10)?redirectedfrom=MSDN
Also, check if the WIM and the ADK has the same build version of Windows, if not, it will fail to mount.
Hope this helps with your query,
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