Hi PrashantChavan-6623,
You can execute sp_who2 or sp_WhoIsActive to see if there is any blocking.
Secondly, you can check the execution plan and SQL Server Profiler for the query and see if there are any problems.
Please refer to the following articles which might help you to troubleshooting query:
Troubleshoot Slow-Running Queries In SQL Server
How to identify slow running queries in SQL Server
Best Regards,
Amelia