Hello @Greg Brandt
Please try the following to enable the php-pgsql extension for PHP on Azure Web Apps:
Install extension
echo "deb http://ftp.de.debian.org/debian buster main" >> /etc/apt/sources.list
apt-get update && apt-get install -y libpq-dev
docker-php-ext-configure pgsql -with-pgsql=/usr/local/pgsql
docker-php-ext-install pdo pdo_pgsql pgsql
Follow the guide of https://azure.microsoft.com/en-us/documentation/articles/web-sites-php-configure/#how-to-enable-extensions-in-the-default-php-runtime to configure in PHP runtime.
Restart the site after configuring the settings.