Hello
Thank you for your question and reaching out.
I am afraid as you can not buy Microsoft Symbols server as Microsoft doesn't provide the PDBs for SLC to prevent creating of cracks to activate Windows.
Run the VS2012 or 2013 , go to Options->Debugging->automatically load symbols for: "all symbols, unless excluded". Click on the blue link and add SLC to the exclude list.
Alternatively , This can also happen if you don't have Modify permissions on the symbol cache directory configured in Tools, Options, Debugging, Symbols then Clean and Rebuild the project.
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