@Rushit Ajudiya Thanks for reaching out. To test this i have created two timer trigger functions in my function app (running with .Net v6.0) using the same CORN expressions ( 0 45 */2 * * * and 0 30 */2 * * *) they are triggering accurately without any issues.
Timer trigger firing might have failed due to the synchronization of triggers. If your function app is hosted on app service plan, then Always On should be enabled. If you are using consumption mode Function app should be woken up when a timer is due. For this to work, your triggers need to be 'synced', which normally happens automatically.
You can refer to this documentation and try to sync your triggers. Additionally, you can refer to this documentation for more information on How to investigate with timer triggered functions not firing.
Feel free to reach back to me if you have any further queries.