As other have said, the data you posted does not result in any constraint violation:
CREATE TABLE Ates (col varchar(200) NOT NULL UNIQUE)
go
INSERT Ates(col)
VALUES('10200 - Kopie'),
('10200 - Kopie - Kopie')
go
yields (2 rows affected).
However, if now attempt to add:
INSERT Ates(col)
VALUES('10200 - Kopie ')
This does indeed result in a constraint violation. In SQL Server trailing spaces does not count as significant when comparing values.