Hi @Jürgen Rausch ,
May I ask do you mean that outlook for android auto-detect this account type is office365 instead of shows the page of select the account type? If I misunderstood your question, please feel free to correct me.
If it is this situation, please have a check which version of outlook. For my test with the version 4.2220.0 , I can click the “back” button in the page of enter password to go to in the page of select the account type. Then reselect and configure to connect to the on-premises Exchange server.
(If there is not back button in the page, you could use the device that comes with it.)
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