
Dear @TantirigamaThilina-7057 ,
Thank you for your post in our forum.
If you set ‘All multiple selections’ to ‘NO’, you can only add one user to each field.
If you set it to ‘Yes’, no evidence or official documentation indicates that there is a limit of users or groups can be added to a Person or Group column. I am afraid you would need to test it on your own to determine the maximum number (if there is).
If you were to add a large number of users to this column, it would be a better idea to add these users to a group and add this group in this column.
Each group can have up to 5,000 users, and you can have up to 10,000 groups per site (site collection).
I hope I can offer you a better experience next time if I have a chance to work with you again.
Yours faithfully,
Renjie Sun
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