Hi MasaLEE-9140,
According to your description, if the account is part of the AdvHelpDeskUser group. if we could only provide Key ID and reason code fields to check.
That means, if we have logged in with system admin account, then we do not have to supply user domain and user ID.
If you have logged in with normal helpdesk account, you have to supply all-User domain, User ID, Key ID, Reason for Drive Unlock.
Did the user logged in to the machine? if No, you may will receive the error "user is not valid for this drive". We could try to log in the problematic machine locally than check.
Meanwhile, The recovery key gets stored in the table "RecoveryandHardwareCore.keys" inside the Recovery and Hardware database.
We could check the SQL server to get the bitlocker recovery key.
https://www.ronnipedersen.com/2016/01/04/how-to-access-the-mbam-bitlocker-recover-keys-directly-in-sql/
Of course, if we have backup the recovery key to DC, we could find the recovery key from DC.
https://www.top-password.com/blog/find-bitlocker-recovery-key-from-active-directory/
Best Regards,
Carl