Active Directory Troubleshooting Replication
1. First try to ping the DC. Second are you able to ping the DSA GUID?If the DC is pingable but GUID is not pinging , see the below link for that.
2. Some ports should be open for AD replication, see the below link for that.
http://technet.microsoft.com/en-us/library/dd772723(WS.10).aspx
3. Use the PortQry for port Troubleshooting. You can use a GUI tool(portqueryui.exe).
http://support.microsoft.com/kb/310099
4. Repadmin command for experts, you can use the repadmin for Replication Troubleshooting:
http://technet.microsoft.com/en-us/library/cc811549(WS.10).aspx
5. Lingering objects prevent Active Directory replication from occurring
http://support.microsoft.com/kb/317097
6. Troubleshooting Active Directory Issues
7. Use Repadmin for finding replication issue.
repadmin /replsum /bysrc /bydest /sort:delta