Hi,
LDAPS is primarily intended to support simple bind requests, so plain text passwords are encrypted when transmitted over the network. To use this functionality the application or service must be specifically written to support LDAPS, as it needs to request a SSL based connection. Typically security and network devices use simple binds when LDAP\S is used.
I don't believe there is any GPO settings that would force normal clients to use LDAPS as the default connections method.
Gary.