Hi,
I suggest you try to remove Word cache via steps below:
Close Word app. Open Finder, press Command + Shift + g
In the window that opens, enter ~/Library/Containers move the folder Microsoft Word to your Desktop. Reopen Word, create a document and test if you can print it.
You can also try these methods:
https://support.apple.com/en-gb/guide/mac-help/mh14001/mac
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