Hi Clarence Koh,
Thanks for posting on Q&A forum. As pre documentation for Supported Azure Active Directory features in Azure AD B2C (See below).
For external invites in B2C you can use user flows and custom policies to manage user
Inviting External Identities guests | You can invite guest users and configure External Identities features such as federation and sign-in with Facebook and Google accounts. | You can invite only a Microsoft account or an Azure AD user as a guest to your Azure AD tenant for accessing applications or managing tenants. For consumer accounts, you use Azure AD B2C user flows and custom policies to manage users and sign-up or sign-in with external identity providers, such as Google or Facebook. |
Please see this great example on GitHub of how to implement user invite flow in Azure B2C for a sample console app (.Net core) demonstrating how to send sign-up email invitation.
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