Dear JasonYan1,
Good day! Thank you for posting to Microsoft Community. We are happy to help you.
From your description It seems you want to know about OneDrive for Business Storage Capacity(Over 5TB)
Thank you for reaching out to us. We appreciate your feedback and suggestions. As a community, we are here to provide suggestions and guidance to assist you. However, we don't have the necessary permissions and tools to perform any back-end testing.
Hello! For your storage needs exceeding 5TB in OneDrive for Business. According to this article ( OneDrive for Business plan 2 "unlimited personal storage") Microsoft will initially provide 1 TB/user of OneDrive for Business storage, which admins can increase to 5 TB/user. Request additional storage by contacting Microsoft support. Storage up to 25 TB/user is provisioned in OneDrive for Business. you can reach our support team by following below steps
If you don’t have the admin permission on your organization you can contact your office 365 administrator to go to Microsoft 365 >> Admin Center-> Support-> New Service Request if you have admin permission you can directly follow the steps upper without contacting administrators help. Please use my below picture as a references or you can refer to this article to check the way how to raise a ticket.
Get support - Microsoft 365 admin | Microsoft Learn

Also you might want to consider Microsoft 365 E3 or E5 plans. Both of these plans come with unlimited OneDrive storage, which should accommodate your 6TB data requirement. These plans also offer additional features and services beyond what's included in the Business Standard subscription.
Microsoft 365 E3 includes advanced security features, compliance tools, and the full desktop version of Office applications. Microsoft 365 E5, on the other hand, offers all the features of E3 and adds advanced analytics, voice capabilities, and more security and compliance features.
for more info Restrictions and limitations in OneDrive and SharePoint
Your understanding and patience will be highly appreciated.
If there is any misunderstanding, please feel free to correct me.
Have a nice day!
Best Regards,
Sophia