Hi Andrea Tordin,
I'm glad that you were able to resolve your issue and thank you for posting your solution so that others experiencing the same thing can easily reference this! Since the Microsoft Q&A community has a policy that "The question author cannot accept their own answer. They can only accept answers by others ", I'll repost your solution in case you'd like to "Accept " the answer.
Issue: You have an Azure WVD host pool with 30 session hosts and want to keep only 1 VM running (besides the one with an active user session) while the others are turned off. Your scaling plan has a minimum percentage of active hosts set to 3%, which seems to result in at least 2 VMs remaining active without sessions. In Peak hours, you can't specify a percentage for idle hosts to remain running. The configuration needs adjustments to meet your goal.
Solution: The setting "Minimum percentage of hosts (%):" was actually fine with the set value 3, the setting I was not considering is Capacity threshold (%): which was configured with set value of 90. To get only 1 running VM as mentioned in previous posts, I had to configure it to 96%.
If you have any other questions or are still running into more issues, please let me know. Thank you again for your time and patience throughout this issue.
Please remember to "Accept Answer" if any answer/reply helped, so that others in the community facing similar issues can easily find the solution.