I don't know if the OP will see this but I had the same issue and figured out how to fix it so for anyone else here's how.
Go to Settings>Display>Graphics>Default graphics settings
At the very top where it gives you a drop down to select your Default high performance GPU select whatever one you want, as long as you change it from "Let windows decide" (For me I have a 6750xt and a 6600 so I selected the 6750xt).
From there go back to Settings>Display>Graphics and select an app then click options (just to see if it worked) and you should see (in my case).
Let windows decide
Power saving: RX 6600
High Performance: RX 6750xt
Specific GPU: (Dropdown)
If the GPU in High Performance and Power Saving are what you want then it worked.