Hi,
Additional network interfaces must be in the same virtual network (VNet) as the network interface that is already attached to the VM. You cannot have a VM with multiple network interfaces attached to different virtual networks. Each network interface can be in a different subnet within the same VNet.
To add another network interface in the portal you first stop the VM and then on the networking blade of the VM you click Attach network interface.
If the above was helpful please click Accept Answer.
Thanks.
-TP