Thank you for asking this question on the Microsoft Q&A Platform.
First, you must determine the reason the emails were filtered as spam or quarantined:
You can determine the reason by viewing the quarantined email in the Microsoft 365 Defender portal at https://security.microsoft.com. The portal provides detailed information about why an email was filtered as spam or quarantined.
Knowing the reason, you can resolve any situation.
If you can determine the reason, please share some screenshots of the quarantine emails.
Hope this helps!
Accept Answer and Upvote, if any of the above helped, this thread can help others in the community looking for remediation for similar issues.
NOTE: To answer you as quickly as possible, please mention me in your reply.