@Justin Lee, Thanks for posting in Q&A. It seems you want to do Hybrid Azure AD join for the devices in your domain.
Based as I know, before we do Hybrid Azure AD join, we can enable password hash to sync the device and user password to Azure AD. As a test, you can choose one OU just with the test device and test user in to sync to Azure AD. Here is a link with more details:
After that, configure Hybrid Azure AD using the steps in the following link. In this link, there are two options. One is for managed domain and the other is for federation domain. If there's no federation domain in your environment, you can choose the steps under managed domain.
https://learn.microsoft.com/en-us/azure/active-directory/devices/howto-hybrid-azure-ad-join
You can verify the hybrid Azure AD join using the steps in the following link:
https://learn.microsoft.com/en-us/azure/active-directory/devices/howto-hybrid-join-verify
Then you can test if anything is affected on the test device. If everything is working, you can enable the password hash for all the devices in the domain to make them Hybrid Azure AD join.
If you want know more about Azure AD connect or Hybrid Azure AD join, you can contact Azure Active Directory support to get more help.
Hope the above information can help.
If the answer is helpful, please click "Accept Answer" and kindly upvote it. If you have extra questions about this answer, please click "Comment".
Note: Please follow the steps in our documentation to enable e-mail notifications if you want to receive the related email notification for this thread.