@SaikrishnaE, Thanks for posting in Q&A.
For apps deployed to Windows 10 or Windows 11 Enterprise multi-session remote desktops, it has some limitation. Please check if the app we deployed is supported:
Meanwhile, to configure configuration policies for Windows 10 or Windows 11 Enterprise multi-session VMs, you'll need to use the Settings catalog in the Microsoft Intune admin center. The existing device configuration profile templates aren't supported for Windows 10 or Windows 11 Enterprise multi-session VMs, except for the Trusted certificate, SCEP certificate, PKCS certificate and VPN profiles.
Hope the above information can help.
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