Hi @Alex.K ,
Came across the following thread which discusses the same error message. And according to the comments there, seems like it could be a backend incident recently. Could you have a look at the Service Health dashboard from your M365 admin center and see if there's anything which might be relevant?
SPO error message when I try to change can email address and add an alias in Office365
Besides, you can try adding the alias email for the user via the Azure portal instead and see if it can work:
https://portal.azure.com/#view/Microsoft_AAD_UsersAndTenants/UserManagementMenuBlade/~/AllUsers
Select the user, click Edit properties, scroll down and choose Add email:
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