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Hi @steve w,
Glad to know the issue has been resolved, thanks for sharing the solution so others with the same issue can easily reference it ! Since the Microsoft Q&A community has a policy that "The question author cannot accept their own answer. They can only accept answers by others", I'll repost your solution in case you'd like to "Accept" the answer : )
[Exchange 2016 ECP / Powershell Error]
Problem symptoms:
Clicking View Details for a user in the ECP creates the error message and EMS errors occur when using the Get-MailboxDatabaseCopyStatus commandlet with or without parameters.
Resolution:
“This turned out to be corruption related and fixing that resolved all my issues along with rebuilding the index to resolve the original issue.”