@James T, Thanks for posting in Q&A. It seems the windows hello for business authentication is failed.
I notice you already tried deleting NGC folder, remove WHFB, delete Windows Hello for Business container and redeploy the policy. But it is still not working. Please check if the device is with the latest update. If not, please install the latest one to see if it works.
Meanwhile, please check the device edition of the affected device to see if it is supported.
In addition, when we remove the policy, please also ensure the registry key on the device is removed. After that, delete NGC folder, delete Windows Hello for Business container, restart and redeploy the policy
However, if the issue still persists, you can reset the device or reinstall OS on this device to deploy again to see if it can work..
Hope the above information can help.
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