Hi TK, I am Paulo and I'd like to help.
You should be able to add a program in Open With if you're able to open the file with that app. Here are the steps:
- Right-click on any .stl file
- Hover on Open with > Choose another app
- Once the list of apps opens, scroll down and click More apps
- Scroll down again then click Look for another app on this PC
- Locate and choose the program
- Once the file has been opened by the app, close it and check if the app is now on the Open with list
- To locate the program, it would be easier to right-click on the app in the Start menu > More > Open file location.
- Once the File Explorer opens the list of Start menu programs, right-click on the shortcut of the app then click on 'Open file location' once again.