Hello,
double check that the values in the cells are numbers, not text that looks like numbers.
- try to format them with fewer or more decimal points. If they don't react, they are text
- in that case, enter a 0 into an empty cell, copy that cell. Select the text cells and use Paste Special > Add. This will add a 0 to the text and convert it to a number at the same time.
When you have established that the values are truly numeric, double check the definition of the XY series data source. Edit each series and check the range that the X values are pointing to.
If that does not help, please replace confidential data with dummy data and share the file. Use a file sharing site or your Onedrive public folder, get a link and post that here.