Your second screen is irrelevant as it is for EAS accounts which is something completely different from Exchange accounts which use Outlook Anywhere.
Having a properly functioning AutoDiscover service running on your Exchange server is a hard requirement to have a supported Exchange configuration. Outlook 2016 also relies on this AutoDiscover service to obtain all the server settings for various functionality; not just for configuring your account.
When your AutoDiscover service has been configured correctly on the Exchange server, all you have to provide in Outlook would be your name, email address and password and Outlook will configure itself without the need to manually alter something.