Hi Frank III
Thank you for contacting the Microsoft Q&A forum.
Based on your description, I understand that your custom domain email (hosted on cPanel/Namecheap) can successfully receive emails in Outlook for Android, but outgoing emails cannot be sent, even though the same IMAP/SMTP settings work correctly in other email applications.
Outlook for Android uses an automated account discovery process to simplify setup. For non-Microsoft mail services (such as cPanel-hosted mailboxes), this process may override or misinterpret manual SMTP settings. As a result, the account may connect successfully for incoming mail (IMAP) but fail when sending email (SMTP). It seems like this behavior is related to the Outlook mobile app, rather than incorrect credentials or server configuration.
Here is recommendation from my side you can try:
Re-add the account using manual IMAP setup
- Remove the account from Outlook for Android and try to re-add it using Manual Setup > IMAP
- Skip or cancel any automatic account detection
- Enter IMAP and SMTP server details manually:
- Open the Outlook App on your phone > Tap the Home/Profile Icon (top left) > Settings (Gear icon) > Tap Add Mail Account > Add an email account > Enter your full email address and tap Continue then while the account is loading, return to the previous page or look for a switch labeled "Advanced" or "Advanced Settings" and toggle it ON.
- For more detailed information, please refer to this article: Set up email in the Outlook for Android app - Microsoft Support



On the "Choose Account Type" screen, you will now see a prompt asking for specific server details. Please fill them in and try again.
Please note that I’m not using the same device as you; I tried it on another Android device. So, some options may have slightly different names, so if there are any differences, you can look for similar names instead)
I hope this information proves helpful. Please try the steps above and let me know how it goes. I am looking forward to your reply.
If the answer is helpful, please click "Accept Answer" and kindly upvote it. If you have extra questions about this answer, please click "Comment".
Note: Please follow the steps in our documentation to enable e-mail notifications if you want to receive the related email notification for this thread.