i found the solution for my Problem(503-Error) in my case. The Problem was that i used Self-Signed Certficate on the AppGw-Listner(for testing the concept)
Solution:
If the AppGW behind Az-Front Door, then you need a valid certificate from CA on the Https-Listner of AppGW instead of Self-Signed Certificate!
And may be you to add a "rule" in Az-FD to disable "Accept-Encoding" for requests!
The Request is working now!
Here is a clue: https://learn.microsoft.com/en-us/azure/frontdoor/end-to-end-tls
Thank you for your Support,
Best regards,