Hi @Han Shih 施學翰 ,
Welcome to Microsoft Q&A! Thanks for posting the question.
I understand that you are trying to test alert rule in Azure monitor. Please note that the alert rules are based on signals which can be of any of the following types: metric, activity log, Application Insights, and log. (ref: Overview of alert rule). For most of these signal types, you can not define a specific time when this checking would happen. It continues to run in the background looking for the signals.
However, some of the alert rule types (for example the Metric based and log based) you can specify the frequency of evaluation - which would not give you the exact time when it will run, but you will get an idea of time period when it is going to run. For example, if you specify the frequency as 5 minutes you may expect the rule to run within the next 5 minutes.
Please let me know if you have any questions.
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