@Darren Persaud, Thanks for posting in Q&A. Based on my researching, for windows 365 cloud PCs, as an admin, you can remotely manage Windows 365 Cloud PCs by using the Microsoft 365 admin center or windows365.microsoft.com. Each supports several remote management actions.
https://learn.microsoft.com/en-us/windows-365/business/device-management
As the Cloud PC is associated with the user account, it is not able to login the user's cloud PC directly using admin account in Windows 365 Cloud PC. You could do it with AVD, but not with Windows 365 because it is heavily Intune managed, more closed VDI system.
Thanks for your understanding.
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