Hi @63470014
If you are looking to implement a hybrid envirement for Exchange, you should start by synchronise on-premise accounts to Entra ID using Entra connect server or Cloudsync.
If you want use ENtra ID connect , you should sync OU of target users. Entra ID cannot sync a user based on group membership .
If you want sync only users membre of a group , in this case you can use Cloud Sync:
Create a new configuration for Microsoft Entra Cloud Sync
Regarding the deployment of Exchange hybridation I invite you to read the following article where you will find all details about all requirement configuration:
Hybrid deployment prerequisites
Exchange Server hybrid deployments
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