NABAKISHOREPANI-0980, Apologies for the delay in responding from over the weekend.
As mentioned in the doc - "Currently, SMS messages can be sent to and received from United States phone numbers. Phone numbers located in other geographies are not yet supported by Communication Services SMS. For more information, see Phone number types.
Also, ensure that the phone numbers should be provided in E.164 international standard format (e.g.: +14255550123). The From phone number may be a Short Code as well (e.g.: 23456).
-You may also checkout a demo on how to send SMS via ACS: https://learn.microsoft.com/shows/Hello-World/Hello-World-Azure-Communication-Services
If the issue still persists, please do share the screenshot of the error after concealing any PII info.
Kindly let us know, I'll follow-up with you further.